2-D transition metal carbides (TMCs)-based anode materials offer competitive performance in lithium-ion batteries (LIBs) owing to its excellent conductivity; cheaper, flexible uses; and superior mechanical stability. However, the electrochemical energy storage of TMCs is still the major obstacle due to their modest capacity and the trends of restacking/aggregation. In this report, the Mo2C nanosheets were attached on conductive CNT network to form a hierarchical 2D hybrid structure, which not only alleviated the aggregation of the Mo2C nanoparticle and facilitated the rapid transference of ion/electron, but also adapted effectually to the hefty volume expansion of Mo2C nanosheets and prevented restacking/collapse of Mo2C structure. Benefitting from the layered Mo2@CNT hybrid structure, the charge/discharge profile produced a 200 mAh g