Transition metal dichalcogenides (TMDs) are the auspicious inexpensive electrocatalysts for the hydrogen evolution reaction (HER) which has been broadly studied owing to their remarkable enactment, however the drought of factors understanding were highly influenced to hinder their electrocatalytic behavior. Recently, transition metal carbide (TMC) has also emerged as an attractive electrode material due to their excellent ionic and electronic transport behavior. In this work, Mo2C@WS2 hybrids have been fabricated through a simple chemical reaction method. Constructed heterostructure electrocatalyts presented the small Tafel slope of 59 and 95 mV per decade and low overpotential of 93 mV and 98 @10 mA·cm−2 for HER in acidic and alkaline solution, respectively. In addition, 24-h robust stability with the improved interfacial interaction demonstrated the suitability of hybrid electrocatalyst for HER than their pure form of Mo2C and WS2 structures. The derived outcomes describe the generated abundant active sites and conductivity enhancement in TMC/TMD heterostructure along with the weaken ion/electron diffusion resistance for efficient energy generation applications.