연구 Highlight

[구두발표]Highly conductive and thermally stable doped MWCNTs synthesized by arc discharge and their superior field emission properties

  • 저자명

    Syed Muhammad Zain Mehdi, Naesung Lee

  • 학회명

    Nano Korea 2021

  • 게재권/집

  • 페이지

  • 발표일

    2021-07-09

  • URL
Carbon nanotubes (CNTs) have drawn much attention as one of the idealma terials for field emitters due to their unique properties such as sharp tip geometry and large aspect ratios, excellent mechanical strength, superior chemical stability and high melting point. Their outstanding field emission performance and commercial mass production have led CNTs to be most promising for various industrial potential applications including x-ray tubes, flat lamps, flat electron sources, electron microscopes, field emission displays, etc. Among several approaches for fabrication of CNT field emitters, a screen-printing technology is most preferred due to scalability, low cost and design tlexibility of field emitters. In this work, we investigate optimalde sign of CNTp astes for best field emission performance and, for this purpose, fabricate CNT pastes based on a Ni-Si-Al2O3 filler system.  Performance of screen-printed CNT emitters greatly is affected by adhesion and cohesion strength of the pastes because large electrostatic forces are generated on
them during operation offield emitters.  If the pastes have low adhesion and cohesion strengths, CNT emitters may be pulled out, causing catastrophic electric arc. To improve cohesion and adhesion strength, screen printed CNT emitters were annealed at 865 oC in a high vacuum condition. At high temperature, Si nanoparticles formed strong covalent bonds with Ni nanoparticles to enhance cohesion strength of the CNT paste. In addition, Si nanoparticle chemicaly reacted with Fe in the Kovar(Ni29Co17 ferrous aloy) substrate, forming strong covalent bonds and improving the adhesion strength. In this work, we fabricate high-performance CNT paste emitters having a capability of generating high current density of 14 Acm-2 in a diode configuration